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The solution reactions of the metal salts with 2,2′-bipyridine (2,2′-bipy) and ethyl tetrazole-5-carboxylate (Hetzc) afforded two new tetrazole-based complexes M(2,2′-bipy)2(etzc)2 (M = Mn 1, Zn 2), and their crystal structures were determined by single-c