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１９８８年，Ｓｈａｒｐｌｅｓｓ等［１］发现金鸡纳生物碱（Ｃｉｎｃｈｏｎａａｌｋａｌｏｉｄ）的衍生物对烯烃的不对称双羟基化反应（ＡＤ）具有很高的不对称诱导活性，反应式如下：Ｒ１Ｒ２ＯｓＯ４／Ｌ＊Ｋ３Ｆｅ（ＣＮ）６／Ｋ２ＣＯ３→ＨＯ＊Ｒ１＊Ｒ２ＯＨ烯烃的...
In 1988, Sharpless et al. [1] found that derivatives of Cinchona alkaloid have high asymmetric induction activity on the asymmetric dihydroxylation of olefins (AD). The reaction equation is as follows: R1R2OsO4 / L * K3Fe CN) 6 / K2CO3 → HO * R1 * R2OH Olefin ...