The polarized Raman spectrum of NaBF_4 single crystal measured by use of different geometric arrangements are reported. The obvious anisotropy of the crystal results in the degradation of degenerated modes of BF_4. Experiments show that the vibration frequencies decrease with the increasing of temperature. But when it above the phase transition point the v_1 symmetric stretching vibration is restored. From this, the phase transition temperature can be estimated to be 250℃ (523K). The polarized anisotropy of the crystal results in the degradation of degenerated modes of BF_4. Experiments show that the vibration frequencies decrease with the increasing of temperature. But when it above the phase transition point the v_1 symmetric stretching vibration is restored. From this, the phase transition temperature can be estimated to be 250 ° C (523K).