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The reactions LnCl3(s)+(3/2)Al2Cl6(g)=LnAl3Cl12(g) for Ln=La to Lu were studied by quenching experi-ments in roughly the same temperature and pressure ranges (588-851 K and 0.01-0.02 MPa).Stability constants K^- of lanthanide complexes LnAl3Cl12 were calc