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双金属催化剂是一类重要的多相催化剂。其中d电子在催化活性方面起着重要的作用.本文在Co_3[Fe(CN)_6]_2的工作基础上,进一步研究了该配合物在硅胶、氧化铝、以及氧化镁上的热性质,同时考察了CN~-在Co-Fe体系双端基配位的活化加氢,探讨了载体的影响.
Bimetallic catalysts are a class of important heterogeneous catalysts. Among them, d electron plays an important role in the catalytic activity.In this paper, based on the work of Co_3 [Fe (CN) _6] _2, the thermal properties of the complex on silica, alumina and magnesia were further studied. The activation hydrogenation of CN ~ - in the double-terminal coordination of Co-Fe system was investigated, and the influence of carrier was discussed.