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A new complex Zn(Ⅱ)L2·2CH3OH(H2L = 4-chloro-2-(2,3-dihydro-1H-ben-zoimi-dazol-2-yl)-phenol) has been prepared and characterized by single-crystal X-ray diffraction analysis and elemental analysis.The crystal is of triclinic system,space group P1 with a = 9.2905(10),b = 10.3555(13),c = 14.9590(14) ,α = 101.0340(10),β = 101.261(2),γ = 99.1660(10)o,V = 1356.1(3) 3,Z = 2,C28H24Cl2N4O4Zn,Mr = 616.78,Dc = 1.510 g/cm3,μ = 1.145 mm·1,F(000) = 632,the final R = 0.0379 and wR = 0.0830 for 3606 observed reflections with I > 2σ(I).The Zn(Ⅱ) atom presents a distorted square pyramidal coordination involving two H2L ligands.The hydrogen bonds and π···π stacking interactions extend the complex into a two-dimensional framework.
A new complex Zn (II) L2.2CH3OH (H2L = 4-chloro-2- (2,3-dihydro- 1H -benzole-dazol-2-yl) -phenol) has been prepared and characterized by single-crystal X-ray diffraction analysis and elemental analysis. The crystal is of triclinic system, space group P1 with a = 9.2905 (10), b = 10.3555 (13), c = 14.9590 = 101.261 (2) γ = 99.1660 (10) o V = 1356.1 (3) 3 Z = 2 C28H24Cl2N4O4Zn Mr = 616.78 Dc = 1.510 g / cm3 μ = 1.145 mm · 1 F ) = 632, the final R = 0.0379 and wR = 0.0830 for 3606 observed reflections with I> 2σ (I). The Zn (II) Atoms presents a distorted square pyramidal coordination involving two H2L ligands. The hydrogen bonds and π π stacking interactions extend the complex into a two-dimensional framework.