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高锰酸钾非均相选择性氧化芳烃ZhaoD等[Synthesis,1994:915]芳烃与吸咐在氧化铝上的高锰酸钾,于室温下非均相反应,可选择性氧化芳烃的苄位──CH2R(仲碳)氧化为国,CHR2(叔碳)氧化为醇。18例多数收率中至优。如由苯乙酸乙酯可得...
Potassium Permanganate Heterogeneous Selective Oxidation of aromatics ZhaoD et al [Synthesis, 1994: 915] arene react with potassium permanganate adsorbed on alumina heterogeneously at room temperature to selectively oxidize the benzylic ─ ─ CH2R (secondary carbon) into the country, CHR2 (tertiary carbon) into alcohol. 18 cases of most of the yield to excellent. As can be obtained from ethyl phenylacetate ...