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利用氯化锰与4-氧-1(4H)-吡啶乙酸反应合成了一个新的配合物[Mn(H2O)6](4-OPA)2·2H2O(4-OPA-=4-氧-1(4H)-吡啶乙酸根),并对其进行了元素分析、IR光谱和单晶X射线的表征。配合物晶体属单斜晶系,空间群为P21/c,晶胞参数为a=1.2561(3)nm,b=1.2949(3)nm,c=0.68547(14)nm,β=98.68(3)°。V=1.1022(4)nm3,Z=2,Mr=503.32,最终R=0.0319,wR=0.0827。Mn(Ⅱ)原子与六个水分子配位形成八面体构型,4-氧-1(4H)-吡啶乙酸根作为抗衡阴离子,配阳离子与阴离子之间通过静电吸引和氢键作用形成了三维氢键超分子网络结构。
A new complex [Mn (H2O) 6] (4-OPA) 2 · 2H2O (4-OPA- = 4-oxo-1 (4H) -pyridineacetate), and its elemental analysis, IR spectra and single crystal X-ray characterization. The complex crystal belongs to the monoclinic system with the space group P21 / c and the unit cell parameters are a = 1.2561 (3) nm, b = 1.2949 (3) nm, c = °. V = 1.1022 (4) nm3, Z = 2, Mr = 503.32, final R = 0.0319, wR = 0.0827. The Mn (Ⅱ) atom coordinated with six water molecules to form an octahedral configuration. The 4-oxo-1 (4H) -pyridine acetate was used as the counter anion, and the cation and anion were electrostatically attracted and hydrogen- Hydrogen bond supramolecular network structure.