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过渡金属烯烃络合物长期以来吸引化学工作者的广泛注意,其原因不仅因为这类化合物的研究有助于认识过渡金属原子与有机分子的价键特征,而且也可能促进络合催化理论的发展。这类化合物中,最简单而又典型的一个即Zeise盐K[Pt(C_2H_4)Cl_3]·H_2O,早在1825年就已被制备出来,其晶体结构在五十年代就已有报道,随后又由不同的作者反复测定。无水
The reason that transition metal olefin complexes have long attracted chemists is not only because the study of these compounds has helped to understand the valence bond characteristics of transition metal atoms and organic molecules but also may promote the development of complex catalysis theory . Among these compounds, the simplest and most typical Zeise salt K [Pt (C 2 H 4) Cl 3] H 2 O has been prepared since 1825 and its crystal structure has been reported in the 1950s. Repeated determination by different authors. No water