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总结了近年来含氮配体的分子内邻位钯化反应,分析了钯化试剂、金属环大小、溶剂以及底物结构等因素对钯化反应的影响以及它们在有机合成中的应用,讨论了邻位钯化反应的机制。
The intramolecular palladium reaction of nitrogen-containing ligands in recent years was summarized. The effects of palladium reagents, size of metal ring, solvent and substrate structure on the palladium reaction and their application in organic synthesis were discussed. The mechanism of vicinal palladium reaction.