以原位形成的膦钌络合物为催化剂,研究了含氢硅油对酰胺的还原反应,考察了酰胺的结构、反应溶剂、配体等条件对催化反应的催化效率及产物结构的影响.仲胺基及伯胺的酰胺化合物被还原成相应的叔胺及仲胺;丙烯酰胺与含氢硅油反应时,选择性较差,得到丙烯腈、丙腈及与硅烷基相连的聚丙烯酰胺与聚丙烯腈. The phosphine ruthenium complex formed in situ was used as a catalyst to study the reduction reaction of the hydrogen-containing silicone oil on the amide. The effects of the structure of the amide, the reaction solvent and the ligand on the catalytic efficiency and product structure of the catalytic reaction were investigated. Amine and primary amine amide compounds are reduced to the corresponding tertiary amine and secondary amine; acrylamide and hydrogen-containing silicone oil reaction less selective to obtain acrylonitrile, propionitrile and silyl linked polyacrylamide and poly Acrylonitrile.