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研究了NiCrFeMoCoCuW 合金宏观“黑斑”和“白斑”缺陷的形成机制。“黑斑”区富集元素主要以数量较多,尺寸较大的富含钼、钨的M6C和AB3C 等相和数量较多的粒状M6C 的形式存在于晶界上,因界面效应使晶界相对易受侵蚀;“白斑”区晶界主要富含钼、钨的μ相,比富含铬的M6C 基底区耐晶界腐蚀。
The formation mechanism of macro “black spots” and “white spots” defects in NiCrFeMoCoCuW alloy was studied. In the “dark spot” region, the enrichment elements mainly exist in the grain boundaries in the form of a large number of M6C and the larger and larger M6C and AB3C phases and a larger number of granular M6C phases, Relatively susceptible to erosion; the “white spot” zone mainly contains molybdenum and tungsten phases, which are more resistant to grain boundary corrosion than the chromium-rich M6C zone.