【摘 要】
：
Amphiphilic ODA/HY and ODA/ Hβ zeolites have been prepared via chemically coating octadecylamine (ODA) with alcohol as solvent. IR and titrimetric results indi
【机 构】
：
Key Laboratory of Mesoscopic Chemistry of the Ministry of Education
【基金项目】
：
the Opening Test Fund of Nanjing University;国家自然科学基金
论文部分内容阅读
Amphiphilic ODA/HY and ODA/ Hβ zeolites have been prepared via chemically coating octadecylamine (ODA) with alcohol as solvent. IR and titrimetric results indicate that ODA molecules are chemisorbed on the acidic sites in zeolite, showing the higher thermostability and alcohol-resistance. These amphiphilic zeolites contain both the hydrophobic and hydrophilic groups, orient at the liquid-liquid phase-boundary in both cyclohexane/water and water/carbon tetrachloride systems, and exhibit the potential to be used in the phase-boundary catalysis and adsorption. No by-products with strong acidity are formed in this approach, therefore, it can be used to prepare amphiphilic acidic zeolites with low Si/Al ratio.
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