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The autoionization distribution of the triply excited double Rydberg states (TEDRS) 5d5/2NLnl (N _< 22; n _<50; L, l < 4) of La has been investigated by using five-laser resonance excitation in combination with a method of sequential ionization by a pulsed electric field and a constant electric field. The experimental results exhibit that the La atoms in TEDRS predominantly single-autoionize to the ionic Rydberg states located in a few Rydberg manifolds. Furthermore, a difference of autoionization mechanisms between TEDRS above and those below the double ionization threshold is found.