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The organic-inorganic hybrid polymer [Mn(mbbimb)2(1,5-nds)]n 1 has been synthesized using 1,5-naphthalenedisulfonate (1,5-nds) and 1,3-bis(benzimidazol-1-ylmethyl)- 2,4, 6-trimethylbenzene (mbbimb) with Mn(OAC)2·4H2O in solvothermal reaction. The X-ray crystal structure analysis indicates that 1 crystallizes in monoclinic, space group C2/c with a = 21.3546(17), b = 11.8841(7), c = 22.1588(16) , β = 108.058(3)°, C60H54MnN8O6S2, Mr = 1102.17, Ζ = 4, V = 5346.5(7) 3, Dc = 1.369 g/cm3, μ = 0.386 mm-1, F(000) = 2300, S = 1.091, R = 0.0634 and wR = 0.1559 for 4641 observed reflections (I > 2σ(I)). The Mn center is six-coordinated to furnish a distorted octahedral geometry, and the overall framework is a 6-con- nected 3D net.
The organic-inorganic hybrid polymer [Mn (mbbimb) 2 (1,5-nds)] n 1 has been synthesized using 1,5-naphthalenedisulfonate (1,5 -nds) and 1,3-bis The X-ray crystal structure analysis indicates that 1 crystallizes in monoclinic space group C2 / c with a = 21.3546 (17) , B = 11.8841 (7), c = 22.1588 (16) β, β = 108.058 (3) ° C60H54MnN8O6S2, Mr = 1102.17, Ζ = 4, V = 5346.5 73, Dc = 1.369 g / cm3, μ = 0.386 mm -1, F (000) = 2300, S = 1.091, R = 0.0634 and wR = 0.1559 for 4641 observed reflections (I> 2σ (I)). The Mn center is six- coordinated to furnish a distorted octahedral geometry, and the overall framework is a 6-con- nected 3D net.