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A hybrid organic-inorganic material (H2enMe)[Mo3O10] (C3H12Mo3N2O10, Mr = 523.97) has been synthesized under hydrothermal conditions and its crystal structure was determined by X-ray diffraction. It crystallizes in the orthorhombic system, space group Pnma with a = 12.430(2), b = 7.6089(12), c = 11.9553(19) , V = 1130.7(3) 3, Dc = 3.078 g/cm3, Z = 4, μ(MoKa) = 3.328 mm1, F(000) = 1000, the final R = 0.0256 and wR = 0.0716 for 1314 observed reflections with I > 2σ(I). A total of 11780 reflections were measured and 1325 were unique (Rint = 0.0244). It consists of infinite one-dimensional edge-sharing MoO6 octahedral chains with [Mo3O10]2 moieties. The protonated diaminopropane cations are located between the chains and linked to the oxygen atoms of the inorganic skeletal backbones by hydrogen bonds. It is indicated that the as-synthesized compound displays photochromic property in the solid state.
It was crystallized in the orthorhombic system, space group Pnma with a = 0, and the crystal structure was determined by X-ray diffraction. A hybrid organic-inorganic material (H2enMe) [Mo3O10] (C3H12Mo3N2O10, Mr = 523.97) 12.430 (2) b = 7.6089 (12) c = 11.9553 (19) V = 1130.7 (3) 3 Dc = 3.078 g / cm3 Z = 4 MoKa = 3.328 mm1 F = 1000, the final R = 0.0256 and wR = 0.0716 for 1314 were observed with reflections with I> 2σ (I). A total of 11780 reflections were measured and 1325 were unique (Rint = 0.0244) The MoO6 octahedral chains with [Mo3O10] 2 moieties. The protonated diaminopropane cations are located between the chains and linked to the oxygen atoms of the inorganic skeletal backbones by hydrogen bonds. It is indicated that the as-synthesized compound displays photochromic property in the solid state.