Effects of CeO_2 on structure and properties of Ni-Mn-K/bauxite catalysts for water-gas shift reacti

来源 :Journal of Rare Earths | 被引量 : 0次 | 上传用户:ray361
下载到本地 , 更方便阅读
声明 : 本文档内容版权归属内容提供方 , 如果您对本文有版权争议 , 可与客服联系进行内容授权或下架
论文部分内容阅读
Multiple-metal catalysts (Ni-Mn-Ce-K/bauxite) for Water-Gas Shift (WGS) reaction were prepared by impregnation, and the catalytic structure and properties were investigated by N2 physical, XRD, H2-TPR, and CO-TPD. The results indicated that the addition of 7.5% CeO2 improved the activity of the WGS reaction obviously, and also increased the specific surface area and pore volume of the catalysts. The addition of CeO2 decreases the reduction temperature, enhanced the adsorption and activation of H2O, and improved the adsorption content of CO. Besides, active sites were not changed and the number of active sites on catalysts did not increase obviously. Multiple-metal catalysts (Ni-Mn-Ce-K / bauxite) for Water-Gas Shift (WGS) reaction were prepared by impregnation, and the catalytic structure and properties were investigated by N2 physical, XRD, H2-TPR, and CO- TPD. The results indicated that the addition of 7.5% CeO2 improved the activity of the WGS reaction obviously, and also increased the specific surface area and pore volume of the catalysts. The addition of CeO2 decreases the reduction temperature, enhanced the adsorption and activation of H2O, and improved the adsorption content of CO. Besides, active sites were not changed and the number of active sites on catalysts did not increase obviously.
其他文献
(世=《世界电影之窗》应=应亮)■世:从表面上看《另一半》是一部关于爱情和两性关系的电影,当时是怎么考虑选择这样一个题材的?□应:最初刺激我的倒不是这种关系,而是一次偶
笔者所在学校数学教研组在常规教研活动之外,每周五都有一个例行的“解题比赛”活动(教研组所有教师在会议室做一份中考试卷)。有一次解题活动中,选取的是2016年长沙市中考数
水热法合成了3个层状异核金属化合物[Ln(idaH)M(ida)2]n·0.5nH2O,(H2ida=亚氨基二乙酸,Ln=Nd,M=Co(1);Ln=La,M=Co(2);Ln=La,M=Ni(3))。进行了晶体结构测定,红外光谱分析、能
小儿气管内异物是耳鼻喉科常见的急症;异物取出术危险性极大,术中因缺氧可导致严重后果。术中如何有效地给氧是让患儿安全度过手术期的关键。笔者观察了56例小儿气管异物取
正受益于沿海城市产业发展西迁和国家西部大开发战略实施,西部市场的航空航天、通信、轨道交通、汽车电子以及物联网等领域迎来产业升级和发展的大好时期,由此将带动相关电子
为了明确不同剪切方式对沥青面层与半刚性基层层间抗剪切性能的影响,本文拟自行研发室内试验用斜剪、直剪和扭剪试验仪器,分别对不同沥青面层与半刚性基层层间处置措施进行抗
看着各个网站上列出的大学生电影节的入围名单、得奖名单、活动内容、参与人士,我觉察不出任何“大学生”的痕迹。不同的电影奖,从理论上说,应当反映不同人群的审美趣味。专
常识揄的难点是前提知识的不完备性、揄规则的不精确性以及知识中显性或隐性矛盾存在的普遍性。常识推理的第一个特点是“常识性”,“常识 Difficulties in common sense ar
“伟大”这个词,因为过去有一个时期,被我们用滥了,所以后来一见到这个词,就觉得有些发硬,放到哪里都有一种跪下容禀的讨好感。有时即使非 The word “great”, because the
我们正面临绝佳的历史机遇。中国电影大发展大繁荣的潮头已然到来。日前参加在京举行的2008全国电影工作会议,记者感受到这一点,现将在这次会议上国家广电总局关于电影大发展