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用光度法和稀释法分别测算了有机磷一元酸钴四面体加合水反应的ΔＨ和ΔＳ值及有机酸磷的钠盐－水－正辛醇－正辛烷微乳液体系中正辛醇从连续油相转移至界面层的ΔＧ０ｏ－ｉ。得出四面体钴萃合物加合水的趋势与微乳液形成的趋势一致。四面体钴萃合物加合水反应必需通过微乳液才得以进行
The values of ΔH and ΔS of the organophosphorus monoacid cobalt tetrahedron adducted water reaction and the concentration of n-octanol in the sodium salt-water-n-octanol-n-octane microemulsion of organic acid phosphorus were calculated respectively from the continuous The oil phase is transferred to the interface layer ΔG0o-i. The trend of tetrahedral cobalt complex adducting water is consistent with that of microemulsion formation. Tetrahedral cobalt complex addition water reaction must be carried out through the microemulsion