论文部分内容阅读
本文采用溶液法以单酚（４－氯－４’－羟基二苯砜）为原料合成了不同聚合度的单酚低聚体，得到了控制聚合度的最佳聚合条件；用相转移催化剂法成功地将单酚转化为单烯大分子单体，并用ＩＲ、１Ｈ—ＮＭＲ对其结构进行了表征；测定了双键官能度均在１．９０以上．单烯大分子单体与苯乙烯的共聚研究表明，聚合度为２左右的单烯大单体在苯乙烯中溶解度最大，可达８０％以上；共聚物有优异的光学特性，对折射率的提高比相应的双烯大分子单体有利；在可见及近红外区透光率达８９％以上．
In this paper, monophenol oligomers with different degree of polymerization were synthesized by the solution method using monophenols (4-chloro-4’-hydroxydiphenylsulfone) as raw materials, and the optimum polymerization conditions for controlling the degree of polymerization were obtained. The conversion of monophenol to mono-olefin macromonomer was successfully carried out. The structure was characterized by IR and 1H-NMR. The double bond functionalities were all above 1.90. The copolymerization of mono-olefin macromonomer and styrene showed that the degree of polymerization of about 2 is the largest solubility of styrene in the monomer, up to 80%; copolymer has excellent optical properties of the refractive index Higher than the corresponding diene macromonomer favorable; in the visible and near infrared transmittance of more than 89%.