论文部分内容阅读
利用量热法测定了２９８．１５Ｋ时葡萄糖在一些醇（甲醇、乙醇、１－丙醇、１－丁醇）与甲酰胺的混合溶剂中的溶解热．采用ＭｃＭｉｌａｎ－Ｍａｙｅｒ方法，将溶液热力学过量性质与溶液中粒子的相互作用参数相关联，求得了粒子间的焓对相互作用参数和三分子相互作用参数，并就溶质－溶质间的相互作用及溶剂的影响进行了讨论
The heat of dissolution of glucose in a mixed solvent of some alcohols (methanol, ethanol, 1-propanol, 1-butanol) and formamide was measured by calorimetry at 298.15K. The McMilan-Mayer method was used to correlate the excess thermodynamic properties of the solution with the interaction parameters of the particles in the solution. The enthalpy-interaction parameters and the three-molecule interaction parameters between the particles were obtained. The solute-solute interaction and solvent The impact of the discussion