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利用程序升温电导法(TPEC)和程序升温还原法(TPR),研究比较了还原气氛下Pt/MoO_3和Pt/Co_3O_4体系中不同类型的半导体氧化物和吸附氢之间电荷和物种交换的规律.发现微量Pt通过吸附解离H_2成为原子氢,在较低温度下大大加快n型半导体氧化物MoO_3和氢之间电子传递速度,显著地降低MoO_3的还原温度,但在同样条件下却不能有效地活跃p型半导体氧化物Co_3O_4和氢之间的电子传递,因而不能明显地促进Co_3O_4的还原.导致此现象的原因,可能与不同类型的半导体导电机构不同而引起的对氢的敏感程度不同有密切关系.
The temperature-programmed conductance (TPEC) and temperature-programmed reduction (TPR) were used to study the charge and species exchange between different types of oxides and adsorbed hydrogen in Pt / MoO 3 and Pt / Co 3 O 4 systems under reducing atmosphere. It is found that trace Pt dissociates H 2 to atomic hydrogen by adsorption and greatly accelerates the electron transfer rate between the n-type oxide semiconductor MoO 3 and hydrogen at a relatively low temperature, thereby remarkably reducing the reduction temperature of MoO 3 but not effectively under the same conditions The electron transfer between the active p-type semiconductor oxide Co_3O_4 and hydrogen is active, and thus the reduction of Co_3O_4 can not be significantly promoted. The cause of this phenomenon may be different with different types of semiconductor conductive mechanism caused by the hydrogen sensitivity is closely related to different levels.