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在温和的水热条件下,以4,4′-二(1-咪唑基)苯硫醚(BIDPT)和邻苯二甲酸(H2pht)为配体,合成了2个配位聚合物{[Zn(BIDPT)(pht)]2·2H2O·CH3OH}n(1)和{[Cd5(BIDPT)4(pht)5]·H2O}n(2),分别用X-射线单晶衍射、元素分析和IR等手段对它们进行了表征。结果表明,配位聚合物1和2为2D层状结构,配位聚合物1属于正交晶系,Pbcn空间群;配位聚合物2属于三斜晶系,P21/c空间群。此外还考察了1和2的热稳定性和固体荧光性质。
Under mild hydrothermal conditions, two coordination polymers, {[Zn (superscript 2 +)] (BIDPT) (pht)] 2 · 2H2O · CH3OH} n (1) and {Cd5 (BIDPT) 4 (pht) 5] · H2O} n IR and other means of their characterization. The results show that the coordination polymers 1 and 2 are 2D layered structures, and the coordination polymer 1 belongs to the orthorhombic and Pbcn space group. The coordination polymer 2 belongs to the triclinic and P21 / c space group. In addition, the thermal stability and solid fluorescence properties of 1 and 2 were investigated.