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Water-soluble polyaniline(PANI), prepared by chemical-oxide and SmBaCuMO5+δ(M=Fe, Co, Ni)(SBCM) powders, prepared by sol-gel method were analyzed through Fourier transform infrared spectroscopy(FT-IR) spectra, X-ray diffraction(XRD), transmission electron microscopy(TEM) and energy dispersive spectroscopy(EDS) respectively, so as to investigate the gas sensitivities of PANI/SmBaCuFeO5+δ(SBCF) and its sensitivity to NH3 under room temperature. The results showed that all of SBCM powders were of double-perovskite structure and PANI was successfully obtained. Under the same condition, the gas sensor based on PANI/SmBaCuFeO5+δ(SBCF) material exhibited higher resistance sensitivity, better selectivity and shorter response-recovery time than others. The resistance sensitivities to NH3 increased with the increasing of atom radius of M in PANI/SBCM.
Water-soluble polyaniline (PANI), prepared by chemical-oxide and SmBaCuMO5 + δ (M = Fe, Co, Ni) (SBCM) powders, prepared by sol- gel method were analyzed through Fourier transform infrared spectroscopy (FT-IR) spectra , X-ray diffraction (XRD), transmission electron microscopy (TEM) and energy dispersive spectroscopy (EDS) respectively, so as to investigate the gas sensitivities of PANI / SmBaCuFeO5 + δ (SBCF) and its sensitivity to NH3 under room temperature. Under the same condition, the gas sensor based on PANI / SmBaCuFeO5 + δ (SBCF) material exhibited higher resistance sensitivity, better selectivity and shorter response-recovery time than others. The resistance sensitivities to NH3 increased with the increasing of atom radius of M in PANI / SBCM.