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在固相条件下合成了四苯基卟啉钕、四 (对羟基苯基 )卟啉钕、四 (对甲氧基苯基 )卟啉钕、四 (对硝基苯基 )卟啉钕四种钕卟啉配合物。并用元素分析、ICP、U V、IR等手段对配合物进行了表征。用循环伏安法研究了它们的电化学性质。实验结果表明 :四种钕卟啉配合物的电化学性质相似。在循环伏安图上均出现了三对氧化还原电位。但由于卟啉环上对位取代基不同 ,峰电位值不同
Neodymium tetraphenylporphyrin, neodymium tetrakis (p-hydroxyphenyl) porphyrin, neodymium tetrakis (p-methoxyphenyl) porphyrin and neodymium tetrakis (p-nitrophenyl) porphyrin were synthesized under solid phase conditions. Species neoporphyrin complexes. The complexes were characterized by elemental analysis, ICP, UV, IR and so on. Their electrochemical properties were investigated by cyclic voltammetry. The experimental results show that the electrochemical properties of the four neoporphyrin complexes are similar. Three cyclic redox potentials were observed on cyclic voltammograms. However, due to the porphyrin ring on the different substituents, the peak potential value is different