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5. The Studies of Rhodium-catalyzed Ring Opening Reaction of N-Boc azabenzonorbornadiene with Heteroato

The Studies of Rhodium-catalyzed Ring Opening Reaction of N-Boc azabenzonorbornadiene with Heteroato

来源 :中国化学快报（英文版） | 被引量 : 0次 | 上传用户：Haroldzhang

【摘 要】

：

A rhodium-catalyzed ring opening reaction of N-Boc-azabenzonorbornadiene with heteroatom nucleophiles was described. Piperidine and piperazine's derivatives wer

【作 者】

：

Er Chang LIU Ding Qiao YANG Yi 

【机 构】

：

School of Chemistry and Environment

【出 处】

：

中国化学快报（英文版）

【发表日期】

：

2004年期

【关键词】

：

Rhodium-catalyzed N-Boc-azabenzonorbomadiene nucleophiles ring opening 

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论文部分内容阅读

A rhodium-catalyzed ring opening reaction of N-Boc-azabenzonorbornadiene with heteroatom nucleophiles was described. Piperidine and piperazine's derivatives were nucleophiles in this reaction. The yields of the products 2a-f are good and the regioselectivity are excellent.

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