Thermohydrogen processing can enhance workability, decrease flow stress and deforming temperature of titanium alloys. In this study, thermohydrogen processing was carried out for metastable b-type TB8 alloy. The microstructures of hydrogenated TB8 alloy were investigated based on scanning electron microscopy(SEM), transmission electronic microscopy(TEM) as well as X-ray diffraction(XRD) analysis. The results reveal that d hydride phase forms in the hydrogenated TB8 alloy, but the amount of b phase increases with hydrogen content increasing. Single b phase appears when the hydrogen content reaches 0.7 wt%. The alloying elements redistribute in the hydrogenated TB8 alloy, and hydrogen leads to the reduction of the alloying elements in b phase. The room-temperature compression tests were performed on a MTS809 machine. It is found that the room-temperature yield strength of hydrogenated TB8 alloy decreases. And minimum yield strength is obtained at a hydrogen content of 0.5 wt%. The ductility does not decrease within 0.7 wt%hydrogen content. These results provide theoretical basis for improving the formability and promoting the applications of TB8 alloy. Thermohydrogen processing can enhance workability, decrease flow stress and deforming temperature of titanium alloys. In this study, thermohydrogen processing was carried out for metastable b-type TB8 alloy. The microstructures of hydrogenated TB8 alloy were investigated based on scanning electron microscopy (SEM), Transmission electron microscopy (TEM) as well as X-ray diffraction (XRD) analysis. The results reveal that d hydride phase forms in the hydrogenated TB8 alloy, but the amount of b phase increases with hydrogen content increasing. Single b phase appears when the the The alloying elements redistribute in the hydrogenated TB8 alloy, and hydrogen leads to the reduction of the alloying elements in b phase. The room-temperature compression tests were performed on a MTS809 machine. It is found that the room -temperature yield strength of hydrogenated TB8 alloy decreases. And minimum yield strength is obtained at a hydrogen content of 0.5 wt%. The ductil ights does not decrease within 0.7 wt% hydrogen content. These results provide theoretical basis for improving the formability and promoting the applications of TB8 alloy.