Influence of Successive Washing on Porous Structure of Pseudoboehmite

来源 :Journal of Natural Gas Chemistry | 被引量 : 0次 | 上传用户:wzw919
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The effect of successive washing instead of traditional intermittent washing on the porous structure of pseudoboehmite was investigated by mercury porosimetry, N2 adsorption and thermal analysis, while the stabilities of different types of crystals were investigated by X-ray diffractometer. Experimental results show that successive washing is a continuation of the aging process of intermittent washing. After a successive washing, the pore types showed no difference with the intermittent washing. During successive washing, the characteristics of the pores in the range of 2-15 nm changed only very little. However, the distributions of the pore radius for pores of 20-50 and 300-1000 nm were obviously influenced. It was shown that the volume of larger pores decreased only to a smaller extent after the successive washing, as compared with that of the intermittent washing, and the pore size was affected by the condition of the successive washing. The roles of physisorbed water, intermicellar liquid, weakly bonded water, as well as the role of stirring, have been discussed. The effect of successive washing instead of traditional intermittent washing on the porous structure of pseudoboehmite was investigated by mercury porosimetry, N2 adsorption and thermal analysis, while the stabilities of different types of crystals were investigated by X-ray diffractometer. Experimental results show that even washing is a continuation of the aging process of intermittent washing. After successive washing, the pore types showed no difference with the intermittent washing. , the distributions of the pore radius for pores of 20-50 and 300-1000 nm were obviously influenced. It was shown that the volume of larger pores was only to a smaller extent after the successive washing, as compared with that of the intermittent washing , and the pore size was affected by the condition of the successive washing. The roles of physisorbed water, intermicellar liquid, weakly bonded water, as well as the role of stirring, have been discussed.
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