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酸催化莰烯与二醇的羟烷氧基化反应是合成标题化合物的可行路线。前人所用酸性催化剂有离子交换树脂及路易斯酸 BF_3·Et_2O。松原义治等报道用离子交换树脂催化茨烯或三环烯分别与乙二醇、1,2-丙二醇反应获得相应的醚,醚化产率分别为42%、33%。Fujioka,Futoshi 等以 BF_3·Et_2O 为催化剂,使莰烯与1,3-丁二醇反应获得产率为34%的醚。迄
The hydroxyalkoxylation of the acid-catalyzed acenaphthylene with the diol is a viable route to the synthesis of the title compound. The former used acidic catalyst ion exchange resin and Lewis acid BF_3 · Et_2O. Matsubara Yoshitsugu and other reports using ion exchange resin catalysis or tricyclic ene ethylene glycol, 1,2-propanediol reaction of the corresponding ether, etherification yields were 42%, 33%. Fujioka, Futoshi et al BF_3 · Et_2O as a catalyst, the camphene and 1,3-butanediol to obtain a yield of 34% ether. until