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In the presence of Et4NCl?H2O,reaction of AgCl with TabHPF6 in MeCN afforded the title complex {(Tab-Tab)[Ag2(μ-Cl)4]·2MeCN}n 1.1 crystallizes in the orthorhombic space group Pbcn with a=16.782(3),b=6.8358(14),c=26.194(5) ,V=3004.9(10) 3,Z=8,μ= 1.817 mm-1,Dc=1.711 g/cm3,T=223 K,C11H16AgCl2N2S,Mr=387.10,F(000)=1544,S=1.160,R=0.0528 and wR=0.0896 for 2732 observed reflections with I > 2σ(I).1 contains a 1D linear [Ag2Cl4]n2n-chain coupled with the [Tab-Tab]2+ dications.Intermolecular hydrogen bonding interac-tions between the protons of methyl groups from the Tab-Tab dications and the chlorides result in the formation of a 2D hydrogen-bonded network.
In the presence of Et4NCl? H2O, reaction of AgCl with TabHPF6 in MeCN afforded the title complex {(Tab-Tab) [Ag2 (μ-Cl) 4] · 2MeCN} n 1.1 crystallizes in the orthorhombic space group Pbcn with a = 16.782 (3), b = 6.8358 (14), c = 26.194 (5) , V = 3004.9 (10) 3, Z = 8, μ = 1.817 mm -1, Dc = 1.711 g / cm 3, T = 223 K , C11H16AgCl2N2S, Mr = 387.10, F (000) = 1544, S = 1.160, R = 0.0528 and wR = 0.0896 for 2732 observed reflections with I> 2σ (I) .1 contains a 1D linear [Ag2Cl4] n2n-chain coupled with the [Tab-Tab] 2+ dications.Intermolecular hydrogen bonding interac-tions between the protons of methyl groups from the Tab-Tab dications and the chlorides result in the formation of a 2D hydrogen-bonded network.