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A metal-organic coordination polymer,[Cd(C_(15)H_(10)N_4)(C_6H_8O_4)]_(2n)(1,C_(15)H_(10)N_4: 2-methyl-pyrazino-[2,3-f][1,10]-phenanthroline(mpphen),C_6H_8O_4:adipate),was synthesized via hydrothermal synthesis.The polymer was characterized by elemental analysis,IR,TG and single-crystal X-ray diffraction.X-ray diffraction shows that 1 is a cadmium polymer constructed by adipate-bridged dinuclear clusters,and each adipate connects two clusters to form a two-dimensional planar structure.Crystal data for 1:monoclinic,space group C2/c,a=22.403(9),b= 16.039(6),c=13.808(6)(?),β=125.262(6)°,V=4051(3)(?)~3,M_r=502.79,D_c=1.649g/cm~3,μ(MoKα)=1.114 mm~(-1),F(000)=2016,Z=8,the final R=0.0509 and wR=0.1054 for 1509 observed reflections(I>2σ(I)).
A metal-organic coordination polymer [Cd (C_ (15) H_ (10) N_4) (C_6H_8O_4)] 2n (1, C_ (15) H_ (10) N_4: 3-f] [1,10] -phenanthroline (mpphen), C_6H_8O_4: adipate) was synthesized via hydrothermal synthesis. The polymer was characterized by elemental analysis, IR, TG and single-crystal X-ray diffraction shows that 1 is a cadmium polymer constructed by adipate-bridged dinuclear clusters, and each adipate connects two clusters to form a two-dimensional planar structure. Crystal data for 1: monoclinic, space group C2 / c, a = 22.403 β = 125.262 (6) °, V = 4051 (3) (?) ~ 3, M_r = 502.79, D_c = 1.649g / cm ~ 3, μ (MoKα) = 1.114 mm -1, F (000) = 2016, Z = 8, the final R = 0.0509 and wR = 0.1054 for 1509 observed reflections (I> 2σ (I)).