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We report on diode-pumped continuous-wave Pr-doped yttrium lithium fluoride[Pr∶YLF]laser and its frequency doubling to 320 nm.The maximum output power of the 640 nm fundamental wave reached 3.44 W with a slope efficiency of about 48.3%.Using a type-Ⅰ phase-matched lithium triborate[LBO]crystal as a frequency doubler,we have achieved 320 nm ultraviolet radiation with a maximum output power of 1.01 W,which is the highest power ever reported under diode pumping,to the best of our knowledge.