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A new Co(II)polymer[Co(tdc)(1,4-bimb)]n1(H2tdc=thiophene-2,3-dicarboxylic acid,1,4-bimb=1,4-bis(imidazol-1-yl)butane)was synthesized under hydrothermal conditions.The compound crystallizes in the monoclinic system,space group C2/c with a=15.643(9),b=8.839