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The title complex,[Mn_2(L)_2(l,3-BDC)_2]·0.25H_2O 1(L=2-(2-chloro-6-fluorophenyl)-1H-imidazo[4,5-f] [1,10]phenanthroline and 1,3-H_2BDC=1,3-benzenedicarboxylic acid) has been obtained by using hydrothermal synthesis and characterized by elemental analysis,IR and single-crystal X-ray diffraction.It crystallizes in monoclinic,space group P2_1/n with a=1.751 68(6) nm,b=1.160 14(4) nm,c=2.585 30(8) nm,β=104.331(4)°,V= 5.0903(3) nm~3,Z=4,C_(54)H_(28.50)Cl_2F_2Mn_2N_8O_(8.25),M_r=l 140.13,D_c=1.488 g·cm~(-3),F(000)=2306,μ(Mo Kα)=0.613 mm~(-1), R =0.060 5 and wR =0.161 6.The compound 1 exhibits two-dimensional wavy layer structures,which are further stacked throughπ-πinteractions to form three-dimensional supramolecular architectures.
The title complex, [Mn_2 (L) _2 (l, 3-BDC) _2] · 0.25H_2O 1 (L = 2- , 10] phenanthroline and 1,3-H 2 BDC = 1,3-benzenedicarboxylic acid) has been obtained by using hydrothermal synthesis and characterized by elemental analysis, IR and single-crystal X-ray diffraction diffraction patterns in monoclinic, space group P2_1 / (4) nm, c = 2.585 30 (8) nm, β = 104.331 (4) °, V = 5.0903 (3) nm ~ 3 and Z = 4 , C_ (54) H_ (28.50) Cl_2F_2Mn_2N_8O_ (8.25), M_r = l 140.13, D_c = 1.488 g · cm -3, F 000 000 = 2306 and Mo Kα = 0.613 mm -1 ), R = 0.0605 and wR = 0.161 6. The compound 1 exhibits two-dimensional wavy layer structures, which are further stacked through [pi] -πinteractions to form three-dimensional supramolecular architectures.