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合成了一种新型具有刚性结构的二茂铁亚胺(3)及其汞化衍生物(4),经红外、核磁、元素分析、高分辨质谱表征,通过X射线衍射确定了其晶体结构。与前人的实验结果进行比较,进一步证实了汞化反应的邻位区域选择性,为制备新型二茂铁亚胺汞化物提供了有力的理论支持。
A new type of ferrocene (3) with a rigid structure and its mercurial derivative (4) were synthesized. Their structures were characterized by IR, 1H NMR, elemental analysis and high resolution mass spectrometry. Compared with the previous experimental results, it further confirms the ortho-region selectivity of the mercury reaction and provides a strong theoretical support for the preparation of novel ferrocene imide compounds.