Powder compacted and sintered Nb2O5 pellets were cathodically polarised against graphite anode in calcium chloride melt at 1173 K to study the influence of various factors on the electrochemical reduction of the oxide.The parameters were;duration and temperature of electrolysis,open porosity of pellets,nature of anode,mode of electrolysis and configuration of the oxide cathode.The experiments were also conducted in KCl,KCl-25 mol％ CaCl2 and NaCl melts to understand the effect of melt composition on the electroreduction.Different Ca-Nb-O and Nb-O intermediates were found in the pellets electrolysed for different durations of time in CaCl2 melt which eventually reduced to Nb.The current efficiency of the process decreased with increasing duration of electrolysis.Decrease in electrolysis temperature from 1173 to 1073 K led to the decrease in the rate of reduction of the oxide pellets.Pellets with high open porosity reduced faster.Carbon contamination of the melt was relatively less when pyrolytic graphite was used as anode.Of all the melts studied,the reduction was found to be better in calcium chloride melt,that too when alumina crucible was used as container of the melt.