,Preparation, Morphology Transformation and Magnetic Behavior of Co3O4 Nano-Leaves

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A series of cubic phase Co3O4 nano-leaves were prepared via a combined approach of solution reaction and calcination.According to x-ray diffraction and electron microscopy,we find that the Co3O4 grain size increases with calcination temperature.This can induce many gaps in the products.M-T and M-H magnetization measurements reveal the typical antiferromagnetic behavior of nano-leaves.The effective moments of the samples prepared at 300,400 and 500℃ are 5.6,5.8 and 5.7μB per formula unit(FU),respectively,larger than the bulk value of 4.14μB/FU.
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