We have studied the high-order harmonic generated by two coherent pulses in argon gas produced by a gas jet. A loop in the relationship of the harmonic intensity versus the absolute values of relative phase difference was observed for non-collinear arrangement. Compared with the collinear arrangement, increase of 10 times of the conversion efficiency for 17th-order harmonic generation at an appropriate relative phase difference was obtained. The calculation of the intensity and phase for the laser field near the focus gives a simple reason for these phenomena.