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含氮配位原子的希夫碱型化合物在分析化学、合成化学、药学等方面有广泛的应用。近十多年来,随着新药物的研制和生物无机化学的发展,其研究正在不断深入。肟类化合物在结构上与希夫碱型化合物主要不同之处是在于它与氮原子相连的基团是羟基,它在适当的条件下可参与金属配位或形成氢键,研究其配位模式有较重要的理论意义。我们合成了一个新的含醚氧链的双肟化合物,2,2'—双[2—(邻甲酰肟苯氧基)乙基]醚(H_2BFO)。本
Schiff base compounds containing nitrogen atoms have a wide range of applications in analytical chemistry, synthetic chemistry, pharmacy and so on. In the recent ten years, with the development of new drugs and the development of bio-inorganic chemistry, its research is continuously deepening. The main difference between oxime compounds and Schiff base compounds is that the group to which they are attached is a hydroxyl group. Under appropriate conditions, the oxime compound can participate in metal coordination or form hydrogen bond and study its coordination mode Have more important theoretical significance. We have synthesized a new bisoxime compound containing ether-oxygen chain, 2,2’-bis [2- (o-formoxime phenoxy) ethyl] ether (H_2BFO). this