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Three crystal architectures, including one organic compound of benzoyl peroxide(1) and two clusters of tri-iron(Ⅲ) and bi-cupper(Ⅱ) with benzoic ligands(2 and 3), were self-assembled by an in situ redox way of benzoyl peroxide oxidants reacting with Mo, Fe and Cu powders, respectively. X-ray crystallographic results show that both the asymmetry tri-iron(Ⅲ) cluster and the benzoylperoxide crystal architecture(2 and 1) with complicated 3D networks were constructed by intermolecular hydrogen-bonding interactions. Contrarily, the symmetrical bi-copper(Ⅱ) cluster crystal architecture(3), only with π-π stacking between paralleled phenyl groups and without any intermole-cular hydrogen-bonding interactions, only presented an 1D zigzag chain along the a-axis.
Three crystal architectures, including one organic compound of benzoyl peroxide (1) and two clusters of tri-iron (Ⅲ) and bi-cupper (Ⅱ) with benzoic ligands (2 and 3), were self-assembled by an in situ redox way of benzoyl peroxide oxidants reacting with Mo, Fe and Cu powders, respectively. X-ray crystallographic results show both both asymmetry tri-iron (III) cluster and the benzoylperoxide crystal architecture (2 and 1) with complicated 3D networks were constructed by intermolecular hydrogen-bonding interactions. Contrarily, the symmetrical bi-copper (II) cluster crystal architecture (3), only with π-π stacking between paralleled phenyl groups and without any intermole-cular hydrogen-bonding interactions, only presented an 1D zigzag chain along the a-axis.