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我们利用铁氰化钾合成镍的高氧化态配合物过程中,合成出两种新型桥式配合物。经过元素分析、可见-紫外光谱和红外光谱的测试,证明它们是氰桥配合物[(NH_3)_4Ni~(II)-NC-Fe~(III)(CN)_5]~-和[(dmg)_2Ni~(IV)-NC-Fe~(III)(CN)_5]~(3-)。
We use potassium ferricyanide synthesis of high-oxidation state of nickel complexes, the synthesis of two new bridge complexes. After elemental analysis, it can be seen that UV-Vis spectra and FT-IR spectra indicate that they are the complexes of [(NH_3) _4Ni ~ (II) -NC-Fe III III CN] _2Ni ~ (IV) -NC-Fe ~ (III) (CN) _5] ~ (3-).