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The structure of a copper(II) polymer, [Cu(IP)(TBZH)]2n 1 (TBZH = thiabendazole, IP = isophthalic acid), has been determined by X-ray crystallography and characterized by elemental analysis, IR spectrum and thermogravimetric analysis. It crystallizes in the monoclinic system, space group P21/n with a = 11.76, b = 10.41, c = 14.08 , β = 104.80°, V = 1666.0(3) 3, Z = 4, Mr = 428.90, Dc = 1.710 g/cm3, F(000) = 868, μ = 1.468 mm-1 and S = 1.001. The 2-D layered gridding architecture of 1 is constructed from isophthalic acid and binuclear copper atoms. Hydrogen bonds and aryl ring π-π stacking interactions in 1 contribute to a supramolecular structure.
The structure of a copper (II) polymer, [Cu (IP) (TBZH)] 2n 1 (TBZH = thiabendazole, IP = isophthalic acid) has been determined by X-ray crystallography and characterized by elemental analysis, IR spectrum and thermogravimetric analysis. It crystallizes in the monoclinic system with space group P21 / n with a = 11.76, b = 10.41, c = 14.08 , β = 104.80 °, V = 1666.0 3, Z = 4, Mr = 428.90, Dc = 1.710 g / cm3, F (000) = 868, μ = 1.468 mm-1 and S = 1.001. The 2-D layered gridding architecture of 1 is constructed from isophthalic acid and binuclear copper atoms. Hydrogen bonds and aryl ring π -π stacking interactions in 1 contribute to a supramolecular structure.