The perceptive multi-dimension structure of Chinese syllables is studied by psychological-physical experiment. The results indicate that FO and duration are interrelated to two main dimensions of the perceptive structure of Chinese syllable. And the prosodic characteristics such as the position of syllable in prosodic hierarchical structure, as well as the stress will be induced the various distribution of syllable in perception space. The perceptive multi-dimension structure of Chinese syllables is studied by psychological-physical experiment. The results indicate that FO and duration are interrelated to two main dimensions of the perceptive structure of Chinese syllable. And the prosodic characteristics such as the position of syllable in prosodic hierarchical structure, as well as the stress will be induced the various distribution of syllable in perception space.