一、引言物质的结构决定物质的性质,旋光性是分子的非对称结构表现出来的性质。它是非对称分子对左、右圆偏振光的折射度不同而产生的。这种不同与非对称分子中各基团的可极化度大小、排布方向和排列顺序有关,这必然与分子的波函数密切相关。在探讨旋光性与分子构型、 I. INTRODUCTION The structure of matter determines the nature of matter, and the optical activity is the nature of the asymmetric structure of molecules. It is the asymmetry of molecules on the left and right circularly polarized light of different refraction arising. This difference is related to the polarizability, arrangement direction and arrangement order of each group in the asymmetric molecule, which is bound to be closely related to the molecular wave function. In the discussion of optical activity and molecular configuration,