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Complex(Et4N)[ VFe3S4Cl3(CH3CN)3 ](1)has been obtained from(NH4)3VS4/FeCl2/NaHS/Et4NCl reaction system in CH3CN solvent and structurally characterized by X-ray diffraction analysis.It crystallizes in orthorhombic space group Pnma(No.62)with a=8.851(2),b=1