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We synthesized one novel Schiff-base ligand by modifying the aromatic aldehyde: H_2L~1(H_2L~1 = N,N?-bis(2-oxy-acetate-3-methoxyl)benzylpropylene(1,3-propane)diamine). [Ni(C_(23)H_(24)N_2O_8)]·6H_2O](1) was prepared by the reaction between H_2L~1 and