Robot’s dynamic motion error and on-line compensation based on multi-axis force sensor are dealt with. It is revealed that the reasons of the error are formed and the relations of the error are delivered. A motion equation of robot’s termination with the error is established, and then, an error matrix and an error compensation matrix of the motion equation are also defined. An on-line error’s compensation method is put forward to decrease the displacement error, which is a degree of millimeter, shown by the result of Simulation of PUMA562 robot.