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3,3’-Bis(5-(N-(4-hydroxylphenyl)imidomethyl)pyrrol-2-yl)pentane 1 has been synthesized and characterized. The crystal of its methanol complex, 1·(CH3OH)2, belongs to the orthorhombic system, space group Pccn with a = 18.094(2), b = 11.6890(16), c = 13.3629(19) , V = 2826.3(7) 3, Z = 8, C14.5H18N2O2, Mr = 252.31, Dc = 1.186 g/cm3, F(000) = 1080 and μ(MoKα) = 0.080 mm-1. The final R = 0.0662 and wR = 0.1801 for 1908 observed reflections with I > 2σ(I), and R = 0.0800 and wR = 0.1948 for all reflections. In the solid state, bridged by included methanol molecules, the molecules of compound 1 form interpenetrated grid structure through N–H···O and O–H···O hydrogen bonds.
The crystal of its methanol complex, 1 (CH3OH) 2, belongs to the 3-Bis (5- (N- (4-hydroxylphenyl) imidomethyl) pyrrol-2-yl) pentane 1 has been synthesized and characterized orthorhombic system, space group Pccn with a = 18.094 (2) b = 11.6890 (16) c = 13.3629 (19) V = 2826.3 (7) 3 Z = 8 C14.5H18N2O2, Mr = 252.31, The final R = 0.0662 and wR = 0.1801 for 1908 observed reflections with I> 2σ (I), and R = 0.0800 and D = 1.186 g / cm3 and F (000) = 1080 and μ (MoKα) wR = 0.1948 for all reflections. In the solid state, bridged by included methanol molecules, the molecules of compound 1 form interpenetrated grid structure through N-H ··· O and O-H · O hydrogen bonds.