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为了对以多种结构类型的混合烷烃为原料的γ辐射磺氯酰化法合成烷基石油横酸钠的反应提高产率,所以对偶氮二异丁腈(AIBN)敏化效应进行了研究,并对其敏化机理进行了探讨。以AIBN作敏化剂进行磺氯酰化反应,可使烷基磺酰氯具有较大的产率。
AIBN sensitization effect was investigated in order to improve the yield of sodium alkyl yaconate by γ-radiation sulfonation of mixed alkanes with various structure types as raw materials. The sensitization mechanism was also discussed. AIBN as a sensitizer sulfoxidation reaction, alkyl sulfonyl chloride can have a larger yield.