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在HCl-Kcl和聚乙烯醇介质中,用单扫示波极谱法得到了两个灵敏的镓(Ⅲ)、铟(Ⅲ)和对氨基苯基荧光酮配合物的吸附波。两波的峰电位依次为-1.0V和-0.65V(vs.SCE),线性范围:镓(Ⅲ)0.008~0.6μg/ml,而铟(Ⅲ)0.001~0.3μg/ml。用于矿石中镓和铟的直接测定,结果满意。文中还探讨了有关反应机理。
The adsorption waveforms of two sensitive complexes of gallium (Ⅲ), indium (Ⅲ) and p-aminophenylfluorone were obtained by single sweep oscillopolarography in HCl-KCl and polyvinyl alcohol media. The peak potentials of the two waves were -1.0V and -0.65V (vs.SCE), respectively. The linear range was 0.008-0.6μg / ml for gallium (Ⅲ) and 0.001-0.0% for indium (Ⅲ). 3 μg / ml. For the direct determination of gallium and indium ore, the results are satisfactory. The paper also discusses the reaction mechanism.