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在碱式碳酸铜与丙二酸水溶液反应后的滤液中加入 1 ,1 0—口菲口罗啉的乙醇溶液 ,放置获得一种蓝色块状的晶体 X—ray衍射显示为三斜P1群 ,a =1 1 .5 60 ( 2 ) ,b =1 1 .75 0 ( 2 ) ,c=1 2 .5 1 0 ( 3) A ,α =92 .1 3( 3) 。,β =1 0 5 .5 0 ( 3) 。,γ =1 0 9.30 ( 3)°,v=1 5 30 6( 5 ) A3,z=2 ,Mr=781 66,F( 0 0 0 ) =80 0 ,Dc=1 .696g/cm3,μ(MoKα) =1 .467mm- 1 ,R =0 .0 392 二聚体 [Cu( 1 ,1 0 -phen) (CH2 (COO) 2 ) (H2 O) ]2 是通过分子间的氢键形成的
After the reaction of basic copper carbonate with malonic acid aqueous solution was added 1, 10-phenanthroline ethanol solution, placed to give a blue block crystal X-ray diffraction showed triclinic P1 group , a = 1 1 .5 60 (2), b = 1 1 .75 0 (2), c = 1 2 .5 1 0 (3) A, α = 92 .1 3 (3). , β = 105.05 (3). , γ = 10.930 (3) °, v = 15306 (5) A3, z = 2, Mr = 781 66, F (0 0 0) = 80 0, Dc = 1 .696 g / cm 3, μ (MoKα) = 1.467mm -1, R = 0.0392 dimer [Cu (1,10-phen) (CH 2 (COO) 2) (H 2 O)] 2 is formed by intermolecular hydrogen bonding of